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Massekhet Horayot deals with mistakes made by Jewish courts and by Jewish leaders, and the atonement sacrifices that are brought as a consequence of those errors.
Although the focus of the tractate deals with the sacrificial service, and it would appear that the proper place for it would have been in Seder Kodashim, it appears in Seder Nezikin because it, too, serves as a continuation and completion of Massekhet Sanhedrin. After learning the rules and regulations that apply to the Jewish court system, and specifically to the Great Sanhedrin that legislates and rules on capital crimes, it is important to also address the issue of how to deal with mistakes. It is impossible to avoid all circumstances of errors and mistakes, so we must be prepared for such situations, including arranging for atonement for them.